What is PI plastic?
Polyimides (PI or often referred to as the brand name Vespel®) are a family of some of the most heat and fire resistant polymers in existence. Low wear rates combined with the ability to work under unlubricated conditions and high pV-rates makes it the ideal material for challenging friction and wear applications, extending lifetime and reducing maintenance costs.
There are many different grades of PI/Polyimide, all with varying characteristics. A comparison of the technical properties can be found in the tab below.
PI does come with its challenges when it comes to machining. A good machining finish can be achieved by keeping tool cutting edges sharp, particularly for parts requiring tight tolerances. Many of the same milling operations employed on metal (especially brass) may be used on PI, except that a far higher spindle speed must be used. Heat build up should be avoided by using a suitable coolant.
Precautions need to be taken with holding to avoid distortion through over tightening.
Here at Penta Precision, we specialise in machining parts requiring tight tolerances and have plenty of experience with machining polyimides. Being a more expensive polymer, you want to be sure that you use an experienced machining company for a low chance of material wastage in order to keep costs in check.
You may also see PI referred to as:
- Vespel®
- TECASINT® (1000, 2000, 4000, 5000 and 8000 series)
- Duratron®
- Meldin®
- Plavis®
- Sintimid®
- Kapton®
- Cirlex®
- Imidez®
Main attributes
- High strength
- Outstanding wear resistance
- High dimensional stability, even up to 260°C
- Long term thermal stability 300°C
- Excellent thermal and electrical insulation
- Good machinability
- Flame retardant
- Creep resistant
- Good chemical resistance
- Resistance to high energy radiation
- Excellent machinability
Note for designers
The superior performance properties of polyimides come at a cost. They should therefore only be chosen should the part in question need the advanced properties; they really are amongst the highest performing engineering plastics on the market today.
UK stock sizes
Here are the standard stock sizes/colours for PI in the UK. Please note we do not supply stock material, the information provided is purely for design and research purposes.
Grades of TECASINT available:
- 1011 natural – 1000 series unfilled
- 1021 black – 1000 series with 15% graphite filler
- 1031 black – 1000 series with 40% graphite filler
- 1061 black – 1000 series with 15% graphite/10% PTFE
- 2011 natural – 2000 series unfilled
- 2021 black – 2000 series with 15% graphite filler
- 2031 black – 2000 series with 40% graphite filler
- 2061 black – 2000 series with 15% graphite/10% PTFE
- 2391 black – 2000 series with 15% MoS2
- 4011 natural – 4000 series unfilled
- 4021 black – 4000 series with 15% graphite filler
- 4111 natural – 4000 series unfilled
- 4121 black – 4000 series with 15% graphite filler
- 5051 grey-grey – 5000 series with 30% glass fibre
- 8001 yellow-brown – 8000 series with 80% PTFE 20% polyimide
- 8061 yellow-brown – 8000 series with 60% PTFE 40% polyimide
TECASINT 1011 natural (unfilled) stock sizes
Varying stock sizes for each grade. Here are the stocked sizes that are available for 1011 natural as an example. Our Estimators can advise you further if you require a different grade/size.
PI Rod
- From 6.35mm - lengths of 250mm and 250mm
- Up to 25.4mm - lengths of 250mm, 500mm and 1000mm
PI Plate
- From 6.35mm x 300mm - lengths of 125mm up to 1000mm
- Up to 40mm x 300mm - lengths of 125mm up to 1000mm
Common applications
- Valves & pumps
- Wear parts & rings
- Bearings & bushings
Technical properties
Here are the properties for the various grades of TECASINT
TECASINT PI Properties
Mechanical properties
Mechanical Properties
|
1011 (natural)
|
1021 (black) |
1031 (black) |
1061 (black) |
2011 (natural) |
2021 (black) |
2031 (black) |
2061 (black) |
2391 (black) |
4011 (natural) |
4021 (black) |
4111 (natural) |
4121 (black) |
5051 (grey-green) |
8001 (yellow-brown) |
8061 (yellow-brown) |
Parameter |
Norm |
Modulus of Elasticity (tensile test) |
3600 MPa |
4000
MPa
|
|
|
370
MPa |
4400
MPa |
6300
MPa |
3900
MPa |
4400
MPa |
4000
MPa |
4943
MPa |
6300
MPa |
6600
MPa |
5800
MPa |
|
|
1mm/min,
23°C |
DIN EN ISO 527-1 |
Tensile Strength |
116
MPa |
97
MPa |
65
MPa |
77
MPa |
118
MPa |
101
MPa |
65
MPa |
63
MPa |
95
MPa |
130
MPa |
93
MPa |
100
MPa |
34
MPa |
94
MPa |
15
MPa |
13
MPa |
50mm/min,
23°C |
DIN EN ISO 527-1 |
Elongation at Break |
3.8% |
2.8% |
2.2% |
2.9% |
4.5% |
3.7% |
2.1% |
2.7% |
2.9% |
4.5% |
3% |
1.7% |
0.5% |
3.4% |
200% |
4% |
50mm/min,
23°C |
DIN EN ISO 527-1 |
Elongation at Break |
6% |
4.5% |
1.4% |
3.6% |
6.1% |
4.6% |
2.2% |
3.3% |
3.6% |
6.0% |
|
|
|
|
|
|
50mm/min,
23°C |
DIN EN ISO 178 |
Elongation at Break |
|
|
|
|
|
|
|
|
|
|
3.4% |
2.5% |
1.8% |
3.1% |
|
|
10mm/min,
23°C |
DIN EN ISO 178 |
Flexural Strength |
170 MPa |
150
MPa |
88
MPa |
120
MPa |
177
MPa |
145
MPa |
87.5
MPa |
89
MPa |
137
MPa |
180
MPa |
131
MPa |
160
MPa |
113
MPa |
163
MPa |
|
29MPa |
10mm/min,
23°C |
DIN EN ISO 178 |
Modulus of Elasticity (flexural test) |
3700 MPa |
4000
MPa |
|
|
3600
MPa |
4300
MPa |
5200
MPa |
3490
MPa |
4136
MPa |
4300
MPa |
4200
MPa |
6100
MPa |
6100
MPa |
6625
MPa |
|
|
2mm/min,
23°C |
DIN EN ISO 178 |
Compression Strength |
500 MPa |
210
MPa |
180
MPa |
227
MPa |
486
MPa |
300
MPa |
131
MPa |
164
MPa |
252
MPa |
40
MPa |
208
MPa |
250
MPa |
200
MPa |
260
MPa |
|
60MPa |
10mm/min,
23°C |
EN ISO 604 |
Compression Strength |
190 MPa |
175
MPa |
|
|
170
MPa |
160
MPa |
124
MPa |
142
MPa |
180
MPa |
185
MPa |
163
MPa |
250
MPa |
183
MPa |
|
|
|
10mm/min, 10% strain, 23°C |
EN ISO 604 |
Compressive Strain at Break |
45% |
20.1% |
|
|
58% |
43% |
12.5% |
16.4% |
35.6% |
|
36% |
25% |
15% |
72% |
|
|
10mm/min, 10% strain, 23°C |
EN ISO 604 |
Compression Modulus |
2000 MPa |
1880
MPa |
|
|
1713
MPa |
1900
MPa |
2027
MPa |
1748
MPa |
2200
MPa |
2100
MPa |
2067
MPa |
2500
MPa |
2200
MPa |
2590
MPa |
|
|
1mm/min,
23°C |
EN ISO 604 |
Impact Strength (Charpy) |
75.8 kJ/m2 |
35.1
kJ/m2 |
16.5
kJ/m2 |
25.8
kJ/m2 |
87.9
kJ/m2 |
36.7
kJ/m2 |
14.2
kJ/m2 |
19.4
kJ/m2 |
|
87
kJ/m2 |
24.4
kJ/m2 |
24
kJ/m2 |
11
kJ/m2 |
27.3
kJ/m2 |
|
5.4
kJ/m2 |
max. 7.5J, 23°C |
DIN EN ISO 179-1eU |
Notched Impact Strength (Charpy) |
5
kJ/m2 |
4.8
kJ/m2 |
3.6
kJ/m2 |
3.9
kJ/m2 |
9.3
kJ/m2 |
2.9
kJ/m2 |
3.3
kJ/m2 |
3.2
kJ/m2 |
|
9.6
kJ/m2 |
4.8
kJ/m2 |
1.1
kJ/m2 |
1.4
kJ/m2 |
5.1
kJ/m2 |
|
2.5
kJ/m2 |
max. 7.5J, 23°C |
DIN EN ISO 179-1eA |
Shore Hardness |
90D |
88D |
85D |
85D |
90D |
87D |
84D |
84D |
90D |
88D |
86D |
90D |
87D |
92D |
65D |
70D |
Shore D, 23°C |
DIN 53505 |
Thermal properties
Thermal Properties
|
1011 (natural)
|
1021 (black) |
1031 (black) |
1061 (black) |
2011 (natural) |
2021 (black) |
2031 (black) |
2061 (black) |
2391 (black) |
4011 (natural) |
4021 (black) |
4111 (natural) |
4121 (black) |
5051 (grey-green) |
8001 (yellow-brown) |
8061 (yellow-brown) |
Parameter |
Norm |
Notes |
Glass Transition Temperature |
368°C |
330°C |
330°C |
330°C |
370°C |
370°C |
370°C |
|
370°C |
260°C |
260°C |
|
|
340°C |
- 20°C |
20°C |
|
|
DMA, maximum loss factor tan d / DIN EN ISO 11357 |
Heat Distortion Temperature |
368°C |
300°C |
|
|
319°C |
335°C |
325°C |
|
|
360°C |
|
470°C |
|
|
|
|
1.85
MPa
|
DIN 53 461 |
|
Service Temperature |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
250°C |
270°C |
long
term |
|
Found in public sources, individual testing regarding application is mandatory |
Service Temperature |
|
|
|
|
|
|
|
|
|
|
|
|
|
300°C |
|
|
short
term |
|
Found in public sources, individual testing regarding application is mandatory |
Thermal Expansion (CLTE) |
4.3 10-5*1/K |
|
|
|
4.3 10-5*1/K |
4.5 10-5*1/K |
|
|
4.7 10-5*1/K |
5.6 10-5*1/K |
5.4 10-5*1/K |
5.2 10-5*1/K |
5.0 10-5*1/K |
|
|
|
50-
200°C |
DIN 53 752 |
Thermal expansion XY/Z axis |
Thermal Expansion (CLTE) |
5.3 10-5*1/K |
|
|
|
5.1 10-5*1/K |
5.44.3 10-5*1/K |
|
|
5.7 10-5*1/K |
7.6 10-5*1/K |
7.3 10-5*1/K |
6.9 10-5*1/K |
6.6 10-5*1/K |
|
|
|
200-300°C |
DIN 53 752 |
Thermal expansion XY/Z axis |
Thermal Expansion (CLTE) |
|
|
|
|
|
|
|
|
|
11.2 10-5*1/K |
10.5 10-5*1/K |
|
|
|
|
|
300-350°C |
DIN 53 752 |
Thermal expansion XY/Z axis |
Thermal Expansion (CLTE) |
|
|
|
|
|
|
|
|
|
|
|
9.9 10-5*1/K |
9.7 10-5*1/K |
|
|
|
300-400°C |
DIN 53 752 |
Thermal expansion XY/Z axis |
Specific Heat |
1.04 J/(g*K) |
1.13 J/(g*K) |
|
|
0.925 J/(g*K) |
|
|
|
|
1.04 J/(g*K) |
|
|
|
1.20 J/(g*K) |
1 J/(g*K) |
1 J/(g*K) |
|
|
|
Thermal Conductivity |
0.22 W/(k*m) |
0.53 W/(k*m) |
|
|
0.22 W/(k*m) |
|
|
|
|
0.4 W/(k*m) |
|
0.35 W/(k*m) |
|
0.4 W/(k*m) |
0.25 W(k*m) |
0.25 W(k*m) |
40°C |
ISO 8302 |
|
Electrical properties
Electrical Properties
|
1011 (natural)
|
1021 (black) |
1031 (black) |
1061 (black) |
2011 (natural) |
2021 (black) |
2031 (black) |
2061 (black) |
2391 (black) |
4011 (natural) |
4021 (black) |
4111 (natural) |
4121 (black) |
5051 (grey-green) |
8001 (yellow-brown) |
8061 (yellow-brown) |
Parameter |
Norm |
Specific Surface Resistance |
1016 O |
|
|
|
1015O |
|
|
|
|
1016 O |
|
1016 O |
|
1014 |
|
|
23°C |
DIN IEC 60093 / ASTM D 257 |
Specific Volume Resistance |
1017 O*cm |
|
|
|
1015
O*cm |
|
|
|
|
1016 O*cm |
|
1016 O*cm |
|
>1014
O*cm |
1018 O*cm |
1017 O*cm |
23°C |
DIN IEC 60093 / ASTM D 257 |
Dielectric Constant |
|
|
|
|
4.2 |
|
|
|
|
3.59 |
|
|
|
3.59 |
|
|
1 kHz, 23°C |
DIN IEC 60250 / ASTM D 150 |
Dielectric Constant |
|
|
|
|
4.1 |
|
|
|
|
|
|
|
|
|
2.3 |
|
10 kHz, 23°C |
DIN IEC 60250 |
Dielectric Constant |
|
|
|
|
4.1 |
|
|
|
|
|
|
|
|
|
|
|
100 kHz, 23°C |
DIN IEC 60250 |
Dielectric Constant |
3.5 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
50 Hz, 23°C |
DIN IEC 60250 |
Dielectric Constant |
|
|
|
|
|
|
|
|
|
|
|
3.7 |
|
|
|
|
1 MHz, 23°C |
ASTM D 150 |
Dielectric Constant |
3.1 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
27 MHz, 23°C |
DIN IEC 60250 |
Dielectric Constant |
|
|
|
|
4.2 |
|
|
|
|
|
|
|
|
|
|
|
100 Hz, 23°C |
DIN IEC 60250 |
Electric Strength DC |
20 kV*mm-1 |
|
|
|
21.8
kV*mm-1 |
|
|
|
|
18 kV*mm-1 |
|
22.7 kV*mm-1 |
|
|
|
|
23°C |
ISO 60243-1 / ASTM D 149 |
Dielectric Loss Factor |
1*10-3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
50 Hz, 23°C |
DIN 53483-1 / ASTM D 150 |
Dielectric Loss Factor |
|
|
|
|
|
|
|
|
|
1*10-3 |
|
|
|
|
|
|
1 kHz, 23°C |
|
Dielectric Loss Factor |
|
|
|
|
|
|
|
|
|
|
|
0.0013 |
|
|
|
|
1 MHz, 23°C |
ASTM D 150 |
Dielectric Loss Factor |
3*10-3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
27 MHz, 23°C |
DIN 53483-1 |
Other properties
Other Properties
|
1011 (natural)
|
1021 (black) |
1031 (black) |
1061 (black) |
2011 (natural) |
2021 (black) |
2031 (black) |
2061 (black) |
2391 (black) |
4011 (natural) |
4021 (black) |
4111 (natural) |
4121 (black) |
5051 (grey-green) |
8001 (yellow-brown) |
8061 (yellow-brown) |
Parameter |
Norm |
Notes |
Water Absorption |
1.08% |
0.51% |
0.42% |
|
0.47% |
0.44% |
1.2% |
0.35% |
0.53% |
0.16% |
0.08% |
0.08% |
0.08% |
0.53% |
0.70% |
1.12% |
24 h in
water,
23°C |
DIN EN ISO 62 |
|
Water Absorption |
3.29% |
1.57% |
|
|
1.65% |
1.55% |
2.18% |
1.5% |
1.58% |
0.6% |
0.53% |
0.2% |
0.38% |
|
|
|
24 h in
water,
80°C |
DIN EN ISO 62 |
|
Flammability (UL94) |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
V0 |
Corresponding
to |
DIN IEC 60695-11-10 |
Corresponding means no
listing at UL (yellow card).
The information might be
taken from resin, stock shape
or estimation. Individual
testing regarding application
conditions is mandatory. |
Oxygen Index |
|
|
|
|
|
|
|
|
|
49% |
|
53% |
|
|
|
|
|
EN ISO 4589-2 |
|
Density |
1.34 g/cm3 |
1.42 g/cm3 |
1.57 g/cm3 |
1.48 g/cm3 |
1.38 g/cm3 |
1.45 g/cm3 |
1.59 g/cm3 |
1.52
g/cm3 |
1.54
g/cm3 |
1.41 g/cm3 |
1.49 g/cm3 |
1.46 g/cm3 |
1.53
g/cm3 |
1.57 g/cm3 |
1.88 g/cm3 |
1.68 g/cm3 |
|
|
|