PI (Polyimide) plastic machined parts

Polyimides (PI, Vespel®) are highly heat- and fire-resistant polymers. Machining can be challenging, so an experienced CNC partner is recommended. This guide covers attributes, applications, finishing options, and UK stock sizes.

Extremely heat- and fire-resistant
Suited for friction & wear applications

PI (Polyimide) plastic machined parts

Polyimides (PI, Vespel®) are highly heat- and fire-resistant polymers. Machining can be challenging, so an experienced CNC partner is recommended. This guide covers attributes, applications, finishing options, and UK stock sizes.

Extremely heat- and fire-resistant
Suited for friction & wear applications

PI (Polyimide) plastic machined parts

Polyimides (PI, Vespel®) are highly heat- and fire-resistant polymers. Machining can be challenging, so an experienced CNC partner is recommended. This guide covers attributes, applications, finishing options, and UK stock sizes.

Extremely heat- and fire-resistant
Suited for friction & wear applications

PI plastic grades we use

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What is PI plastic?

Polyimides (PI or often referred to as the brand name Vespel®) are a family of some of the most heat and fire resistant polymers in existence. Low wear rates combined with the ability to work under unlubricated conditions and high pV-rates makes it the ideal material for challenging friction and wear applications, extending lifetime and reducing maintenance costs.

There are many different grades of PI/Polyimide, all with varying characteristics. A comparison of the technical properties can be found in the tab below.

PI does come with its challenges when it comes to machining. A good machining finish can be achieved by keeping tool cutting edges sharp, particularly for parts requiring tight tolerances. Many of the same milling operations employed on metal (especially brass) may be used on PI, except that a far higher spindle speed must be used. Heat build up should be avoided by using a suitable coolant.

Precautions need to be taken with holding to avoid distortion through over tightening.

Here at Penta Precision, we specialise in machining parts requiring tight tolerances and have plenty of experience with machining polyimides. Being a more expensive polymer, you want to be sure that you use an experienced machining company for a low chance of material wastage in order to keep costs in check.

You may also see PI referred to as:

  • Vespel®
  • TECASINT® (1000, 2000, 4000, 5000 and 8000 series)
  • Duratron®
  • Meldin®
  • Plavis®
  • Sintimid®
  • Kapton®
  • Cirlex®
  • Imidez®

Main attributes

  • High strength
  • Outstanding wear resistance
  • High dimensional stability, even up to 260°C
  • Long term thermal stability 300°C
  • Excellent thermal and electrical insulation
  • Good machinability
  • Flame retardant
  • Creep resistant
  • Good chemical resistance
  • Resistance to high energy radiation
  • Excellent machinability

Note for designers

The superior performance properties of polyimides come at a cost. They should therefore only be chosen should the part in question need the advanced properties; they really are amongst the highest performing engineering plastics on the market today.

UK stock sizes

Here are the standard stock sizes/colours for PI in the UK. Please note we do not supply stock material, the information provided is purely for design and research purposes.

Grades of TECASINT available:

  • 1011 natural – 1000 series unfilled
  • 1021 black – 1000 series with 15% graphite filler
  • 1031 black – 1000 series with 40% graphite filler
  • 1061 black – 1000 series with 15% graphite/10% PTFE
  • 2011 natural – 2000 series unfilled
  • 2021 black – 2000 series with 15% graphite filler
  • 2031 black – 2000 series with 40% graphite filler
  • 2061 black – 2000 series with 15% graphite/10% PTFE
  • 2391 black – 2000 series with 15% MoS2
  • 4011 natural – 4000 series unfilled
  • 4021 black – 4000 series with 15% graphite filler
  • 4111 natural – 4000 series unfilled
  • 4121 black – 4000 series with 15% graphite filler
  • 5051 grey-grey – 5000 series with 30% glass fibre
  • 8001 yellow-brown – 8000 series with 80% PTFE 20% polyimide
  • 8061 yellow-brown – 8000 series with 60% PTFE 40% polyimide

TECASINT 1011 natural (unfilled) stock sizes

Varying stock sizes for each grade. Here are the stocked sizes that are available for 1011 natural as an example. Our Estimators can advise you further if you require a different grade/size.

PI Rod
  • From 6.35mm - lengths of 250mm and 250mm
  • Up to 25.4mm - lengths of 250mm, 500mm and 1000mm
PI Plate
  • From 6.35mm x 300mm - lengths of 125mm up to 1000mm
  • Up to 40mm x 300mm - lengths of 125mm up to 1000mm

Common applications

  • Valves & pumps
  • Wear parts & rings
  • Bearings & bushings

Technical properties

Here are the properties for the various grades of TECASINT

TECASINT PI Properties

Mechanical properties

Mechanical Properties

1011 (natural)

1021 (black) 1031 (black) 1061 (black) 2011 (natural) 2021 (black) 2031 (black) 2061 (black) 2391 (black) 4011 (natural) 4021 (black) 4111 (natural) 4121 (black) 5051 (grey-green) 8001 (yellow-brown) 8061 (yellow-brown) Parameter Norm
Modulus of Elasticity (tensile test) 3600 MPa

4000
MPa

    370
MPa
4400
MPa
6300
MPa
3900
MPa
4400
MPa
4000
MPa
4943
MPa
6300
MPa
6600
MPa
5800
MPa
    1mm/min,
23°C
DIN EN ISO 527-1
Tensile Strength 116
MPa
97
MPa
65
MPa
77
MPa
118
MPa
101
MPa
65
MPa
63
MPa
95
MPa
130
MPa
93
MPa
100
MPa
34
MPa
94
MPa
15
MPa
13
MPa
50mm/min,
23°C
DIN EN ISO 527-1
Elongation at Break 3.8% 2.8% 2.2% 2.9% 4.5% 3.7% 2.1% 2.7% 2.9% 4.5% 3% 1.7% 0.5% 3.4% 200% 4% 50mm/min,
23°C
DIN EN ISO 527-1
Elongation at Break 6% 4.5% 1.4% 3.6% 6.1% 4.6% 2.2% 3.3% 3.6% 6.0%             50mm/min,
23°C
DIN EN ISO 178
Elongation at Break                     3.4% 2.5% 1.8% 3.1%     10mm/min,
23°C
DIN EN ISO 178
Flexural Strength 170 MPa 150
MPa
88
MPa
120
MPa
177
MPa
145
MPa
87.5
MPa
89
MPa
137
MPa
180
MPa
131
MPa
160
MPa
113
MPa
163
MPa
  29MPa 10mm/min,
23°C
DIN EN ISO 178
Modulus of Elasticity (flexural test) 3700 MPa 4000
MPa
    3600
MPa
4300
MPa
5200
MPa
3490
MPa
4136
MPa
4300
MPa
4200
MPa
6100
MPa
6100
MPa
6625
MPa
    2mm/min,
23°C
DIN EN ISO 178
Compression Strength 500 MPa 210
MPa
180
MPa
227
MPa
486
MPa
300
MPa
131
MPa
164
MPa
252
MPa
40
MPa
208
MPa
250
MPa
200
MPa
260
MPa
  60MPa 10mm/min,
23°C
EN ISO 604
Compression Strength 190 MPa 175
MPa
    170
MPa
160
MPa
124
MPa
142
MPa
180
MPa
185
MPa
163
MPa
250
MPa
183
MPa
      10mm/min, 10% strain, 23°C EN ISO 604
Compressive Strain at Break 45% 20.1%     58% 43% 12.5% 16.4% 35.6%   36% 25% 15% 72%     10mm/min, 10% strain, 23°C EN ISO 604
Compression Modulus 2000 MPa 1880
MPa
    1713
MPa
1900
MPa
2027
MPa
1748
MPa
2200
MPa
2100
MPa
2067
MPa
2500
MPa
2200
MPa
2590
MPa
    1mm/min,
23°C
EN ISO 604
Impact Strength (Charpy) 75.8 kJ/m2 35.1
kJ/m2
16.5
kJ/m2
25.8
kJ/m2
87.9
kJ/m2
36.7
kJ/m2
14.2
kJ/m2
19.4
kJ/m2
  87
kJ/m2
24.4
kJ/m2
24
kJ/m2
11
kJ/m2
27.3
kJ/m2
  5.4
kJ/m2
max. 7.5J, 23°C DIN EN ISO 179-1eU
Notched Impact Strength (Charpy) 5
kJ/m2
4.8
kJ/m2
3.6
kJ/m2
3.9
kJ/m2
9.3
kJ/m2
2.9
kJ/m2
3.3
kJ/m2
3.2
kJ/m2
  9.6
kJ/m2
4.8
kJ/m2
1.1
kJ/m2
1.4
kJ/m2
5.1
kJ/m2
  2.5
kJ/m2
max. 7.5J, 23°C DIN EN ISO 179-1eA
Shore Hardness 90D 88D 85D 85D 90D 87D 84D 84D 90D 88D 86D 90D 87D 92D 65D 70D Shore D, 23°C DIN 53505
Thermal properties

Thermal Properties

1011 (natural)

1021 (black) 1031 (black) 1061 (black) 2011 (natural) 2021 (black) 2031 (black) 2061 (black) 2391 (black) 4011 (natural) 4021 (black) 4111 (natural) 4121 (black) 5051 (grey-green) 8001 (yellow-brown) 8061 (yellow-brown) Parameter Norm Notes
Glass Transition Temperature 368°C 330°C 330°C 330°C 370°C 370°C 370°C   370°C 260°C 260°C     340°C - 20°C 20°C     DMA, maximum loss factor tan d / DIN EN ISO 11357
Heat Distortion Temperature 368°C 300°C     319°C 335°C 325°C     360°C   470°C        

1.85
MPa

DIN 53 461  
Service Temperature                             250°C 270°C long
term
  Found in public sources, individual testing regarding application is mandatory 
Service Temperature                           300°C     short
term
  Found in public sources, individual testing regarding application is mandatory 
Thermal Expansion (CLTE) 4.3 10-5*1/K       4.3 10-5*1/K 4.5 10-5*1/K     4.7 10-5*1/K 5.6 10-5*1/K 5.4 10-5*1/K 5.2 10-5*1/K 5.0 10-5*1/K       50-
200°C
DIN 53 752 Thermal expansion XY/Z axis
Thermal Expansion (CLTE) 5.3 10-5*1/K       5.1 10-5*1/K 5.44.3 10-5*1/K     5.7 10-5*1/K 7.6 10-5*1/K 7.3 10-5*1/K 6.9 10-5*1/K 6.6 10-5*1/K       200-300°C DIN 53 752 Thermal expansion XY/Z axis
Thermal Expansion (CLTE)                   11.2 10-5*1/K 10.5 10-5*1/K           300-350°C DIN 53 752 Thermal expansion XY/Z axis
Thermal Expansion (CLTE)                       9.9 10-5*1/K 9.7 10-5*1/K       300-400°C DIN 53 752 Thermal expansion XY/Z axis
Specific Heat 1.04 J/(g*K) 1.13 J/(g*K)     0.925 J/(g*K)         1.04 J/(g*K)       1.20 J/(g*K) 1 J/(g*K) 1 J/(g*K)      
Thermal Conductivity 0.22 W/(k*m) 0.53 W/(k*m)     0.22 W/(k*m)         0.4 W/(k*m)   0.35 W/(k*m)   0.4 W/(k*m) 0.25 W(k*m) 0.25 W(k*m) 40°C ISO 8302  
Electrical properties

Electrical Properties

1011 (natural)

1021 (black) 1031 (black) 1061 (black) 2011 (natural) 2021 (black) 2031 (black) 2061 (black) 2391 (black) 4011 (natural) 4021 (black) 4111 (natural) 4121 (black) 5051 (grey-green) 8001 (yellow-brown) 8061 (yellow-brown) Parameter Norm
Specific Surface Resistance 1016 O       1015O         1016 O   1016 O   1014     23°C DIN IEC 60093 / ASTM D 257
Specific Volume Resistance 1017 O*cm       1015
O*cm
        1016 O*cm   1016 O*cm   >1014 
O*cm
1018 O*cm 1017 O*cm 23°C DIN IEC 60093 / ASTM D 257
Dielectric Constant         4.2         3.59       3.59     1 kHz, 23°C DIN IEC 60250 / ASTM D 150
Dielectric Constant         4.1                   2.3   10 kHz, 23°C DIN IEC 60250
Dielectric Constant         4.1                       100 kHz, 23°C DIN IEC 60250
Dielectric Constant 3.5                               50 Hz, 23°C DIN IEC 60250
Dielectric Constant                       3.7         1 MHz, 23°C ASTM D 150
Dielectric Constant 3.1                               27 MHz, 23°C DIN IEC 60250
Dielectric Constant         4.2                       100 Hz, 23°C DIN IEC 60250
Electric Strength DC 20 kV*mm-1       21.8
kV*mm-1
        18 kV*mm-1   22.7 kV*mm-1         23°C ISO 60243-1 / ASTM D 149
Dielectric Loss Factor 1*10-3                               50 Hz, 23°C DIN 53483-1 / ASTM D 150
Dielectric Loss Factor                   1*10-3             1 kHz, 23°C  
Dielectric Loss Factor                       0.0013         1 MHz, 23°C ASTM D 150
Dielectric Loss Factor 3*10-3                               27 MHz, 23°C DIN 53483-1
Other properties

Other Properties

1011 (natural)

1021 (black) 1031 (black) 1061 (black) 2011 (natural) 2021 (black) 2031 (black) 2061 (black) 2391 (black) 4011 (natural) 4021 (black) 4111 (natural) 4121 (black) 5051 (grey-green) 8001 (yellow-brown) 8061 (yellow-brown) Parameter Norm Notes
Water Absorption 1.08% 0.51% 0.42%   0.47% 0.44% 1.2% 0.35% 0.53% 0.16% 0.08% 0.08% 0.08% 0.53% 0.70% 1.12% 24 h in
water,
23°C
DIN EN ISO 62  
Water Absorption 3.29% 1.57%     1.65% 1.55% 2.18% 1.5% 1.58% 0.6% 0.53% 0.2% 0.38%       24 h in
water,
80°C
DIN EN ISO 62  
Flammability (UL94) V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 V0 Corresponding
to
DIN IEC 60695-11-10 Corresponding means no
listing at UL (yellow card).
The information might be
taken from resin, stock shape
or estimation. Individual
testing regarding application
conditions is mandatory.
Oxygen Index                   49%   53%           EN ISO 4589-2  
Density 1.34 g/cm3 1.42 g/cm3 1.57 g/cm3 1.48 g/cm3 1.38 g/cm3 1.45 g/cm3 1.59 g/cm3 1.52
g/cm3
1.54
g/cm3
1.41 g/cm3 1.49 g/cm3 1.46 g/cm3 1.53
g/cm3
1.57 g/cm3 1.88 g/cm3 1.68 g/cm3      

Industries that use PI plastic

Automotive & Transport

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Automotive & Transport

Military & defence

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Military & defence

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Electronics & computing

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Food processing & packaging

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